James Franco MTV VMA

James Franco has enjoyed an eclectic career.

This Golden Globe winner truly made a name for himself via the Spider-Man franchise. He also played Tristan in Tristan and Isolde, and showed a comedic touch, appearing in Judd Apatow's Pineapple Express. He was also the lead in The Rise of The Planet of The Apes, and will be playing Oz in Oz: The Great and Powerful.